Palyazat cime: "Szilil-amidok, szilil-eszterek es rokonvegyuleteik szintezise,

reakcioi es molekulaszerkezetenek vizsgalata spektroszkopiai,

diffrakcios es kvantumkemiai modszerekkel".

Futamido: 2002-2005.

Ossztamogatas: 5000 eFt

Summary:

"Silyl amides, silyl esters and related compounds:

Synthesis, reactions and investigation of molecular structure by

spectroscopic, X-ray diffraction and quantum chemical methods"

A number of interesting transformations can be observed among the silylated

carboxylic acid derivatives that are important from a synthetic viewpoint and

can be useful for derivatization reactions. We intend to prepare silylated

amides, imides, esters and other related compounds. These could make possible

the synthesis of novel materials and the development of new preparative

methods. The newly synthesized materials will be investigated by spectroscopy

(IR, NMR, UV/VIS, MS), X-ray diffraction and quantum chemical methods. The

mechanism of the silylation reaction will be studied by kinetical measure-

ments. The thermal reactions will be carried out in the presence of different

trapping agents in order to draw conclusions about the direction of the

reactions.

Budapest, 2002. IX. 25.